Conceptual art showing a compound of promethium
Jacqueline DeMink, art; Thomas Dyke/photography; ORNL, UA.S. Dept. of Energy
A new compound containing one of the rarest elements in the world, promethium, has revealed its mysterious properties for the first time.
Promethium only exists naturally in minuscule amounts – Earth’s crust contains just about half a kilogram of the element. In 1945, researchers at Oak Ridge National Laboratory in Tennessee managed to produce it as a byproduct of the Manhattan Project’s plutonium enrichment programme. Its nuclear origins led to its name, after the Greek titan Prometheus, who stole fire and brought it to humans.
It is now routinely produced, albeit in tiny quantities, from the radioactive decay of uranium and can be incorporated in simple compounds for uses like luminous paint or nuclear batteries. But its extremely radioactive nature means it is inherently unstable, making it difficult to form long-lasting compounds that are easy to study. The crystal structures that it does exist in also exert forces on promethium’s chemical bonds, obscuring its fundamental chemistry, such as how long its atomic bonds are and how they form with other compounds.
Now, Alexander Ivanov at Oak Ridge National Laboratory and his colleagues have found a way to form a promethium compound in water. This dampens some of the damaging effects of radioactivity and avoids the obscuring effects of crystal structures, allowing the team to study the element’s chemistry in detail for the first time.
First, they synthesised a compound called bispyrrolidine diglycolamide (PyDGA), which is based on molecules that form compounds with elements similar to promethium. When promethium was added to this molecule in a solution, it formed the compound Pm-PyDGA, which has a bright pink colour due to its electron structure.
Ivanov and his team then fired X-rays at the compound and measured which frequencies it absorbed, revealing how the promethium was chemically bonded. This showed that the bond length between promethium and nearby oxygen atoms was about a quarter of a nanometre, which matched computer simulations they had run.
“It’s rather beautiful chemistry, and to see the delicate pink colour of this complex is a real joy,” says Andrea Sella at University College London.
Information about promethium’s bonding behaviour will help improve processes for producing purer samples in larger quantities from radioactive waste, says Ivanov, and could also be used to design new medical compounds, such as for radioactive imaging or cancer treatment. “This kind of fundamental information could help us to drive new technologies,” he says.
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